GLYPHOSATE IPA 480G/L SL CAS NO.38641-94-0

 

we are a leading manufacture for Glyphosate, product can be offered with good quality and competitive price:

 

Regarding the quality, we follow every step from the purchasing of materials to the initial processing to processing and to the final items, only the front step passed the check, the next step can be continue. We will test the quality again before shipment. Therefore, we  guarantee that all of our products are no problem with FAO standard.

 

As for the price, as a big manufacture, we purchase the raw materials(like PMIDA) in large volunme, the suppliers of raw materials would like to give us the lower price for long term business.

 

Material Safety Data Sheet

 

 

SECTION 1.  CHEMICAL PRODUCT

Product Name: GLYPHOSATE IPA 480G/L SL

Product Class: Herbicide

CAS RN: (1071-83-6 for glyphosate acid), (38641-94-0 (as the IPA))

 

SECTION 2.  COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENT                      CAS RN                          

Glyphosate IPA                       38641-94-0                        480G/L

Water                                        7732-18-5                          balance to 100%

 

SECTION 3.  HEALTH HAZARDS IDENTIFICATION

Emergency Overview:

Appearance and Odor: Light yellow liquid. Odorless.

Warning Statements: Keep out of reach of children. CAUTION. Causes moderate eye irritation. Harmful if swallowed or inhaled. Avoid contact with eyes, skin or clothing. Avoid breathing spray mist. Wash thoroughly with soap and water after handling.

Potential Adverse Health Effects:

Likely Routes of Exposure: Skin contact and inhalation.

Eye Contact: The undiluted product may cause pain, redness and tearing based on toxicity studies.

Skin Contact: This product is no more than slightly toxic and no more than slightly irritating based on toxicity studies.

Ingestion: This product is no more than slightly toxic based on toxicity studies. No significant adverse health effects are expected to develop if only small amounts (less than a mouthful) are swallowed. Ingestion of similar formulations has been reported to produce gastrointestinal discomfort with irritation of the mouth, nausea, vomiting and diarrhea. Oral ingestion of large quantities of one similar product has been reported to result in hypotension and lung edema.

Inhalation: This product is no more than slightly toxic if inhaled based on toxicity studies.

Carcinogenicity:  IARC: No   NTP: No   OSHA: No

 

SECTION 4.  FIRST AID MEASURES

Emergency First Aid Procedures:

If in Eyes: Flush eyes with plenty of water. Call a physician if irritation persists.

If on Skin: Wash thoroughly with soap and water.

If Inhaled: Remove victim to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Get medical attention.

If Swallowed: This product will cause gastrointestinal tract irritation. Immediately dilute by swallowing water or milk. Get medical attention. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.

SECTION 5.  FIRE FIGHTING MEASURES

Extinguishing Media: In case of fire, use water (flood with water), dry chemical, CO2, or alcohol foam.

Unusual Fire And Explosion Hazards: None

Fire Fighting Equipment: Fire fighters and others exposed to products of combustion should wear self-contained breathing apparatus. Equipment should be thoroughly decontaminated after use.

 

SECTION 6.  ACCIDENTAL RELEASE MEASURES

Steps To Be Taken In Case Of Spill Or Leak: Contain large spills with dikes and transfer the material to appropriate containers. Absorb remaining material or small spills with an inert material. Flush residual spill area with water. Large spills that soak into the ground should be dug up, placed in metal drums and disposed of in accordance with instructions provided below. Contact appropriate state agency when considering a land spreading disposal option. Leaking containers should be separated from non-leakers and either the container or its contents transferred to a drum or other non-leaking container and disposed of in accordance with instructions provided below. Any recovered spilled liquid should be collected and disposed of similarly.

 

SECTION 7.  HANDLING AND STORAGE

Handling: Avoid contact with eyes, skin or clothing. Avoid breathing spray mist. Wash thoroughly with soap and water after handling. Wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned, or destroyed. DO NOT REUSE THIS CONTAINER. Spray solutions of this product should be mixed, stored or applied using only stainless steel, aluminum, fiberglass, plastic or plastic-lined containers. DO NOT MIX, STORE OR APPLY THIS PRODUCT OR SPRAY SOLUTIONS OF THIS

PRODUCT IN GALVANIZED OR UNLINED STEEL (EXCEPT STAINLESS STEEL) CONTAINERS OR SPRAY TANKS. This product or spray solutions of this product react with such containers and tanks to produce hydrogen gas that may form a highly combustible gas mixture. This gas mixture could flash or explode, causing serious personal injury, if ignited by open flame, spark, welder’s torch, lighted cigarette or other ignition source.

Storage: Do not contaminate water, foodstuffs, feed or seed by storage or disposal. STORE ABOVE 10°F (-12°C) TO KEEP PRODUCT FROM CRYSTALLIZING. Crystals will settle to the bottom. If allowed to crystallize, place in a warm room 68° F (20° C) for several days to redissolve and shake or roll to mix well before using. Product is stable under normal conditions of storage and handling for at least 5 years. Store in

a cool, well-ventilated place away from foodstuffs, reducing agents and acids.

 

SECTION 8.  EXPOSURE CONTROL/PERSONAL PROTECTION

Eye Protection: Based on usage conditions, consider wearing chemical splash goggles during mixing/pouring operations or other activities in which eye contact with undiluted herbicide is likely to occur. Protective eyewear is not mandatory for mixing, pouring, application or other use of this product in accordance with label directions.

Skin Protection: Wear appropriate protective clothing to avoid skin contact. Applicators and other handlers

cleaning/maintaining PPE. If no such instructions for washables, use detergent and hot water. Keep and wash PPE separately from other laundry.

Respiratory Protection: For Handling of the Undiluted Product: The undiluted herbicide is not likely to present an airborne exposure concern during normal handling. If there is an accidental discharge of the material during manufacture or handling that produces a heavy vapor or mist, workers should use NIOSH/MSHA approved equipment. In work situations where an air purifying respirator is appropriate to be used, use of a full face respirator equipped with purifying elements for protection against organic vapor and dust/mist approved for pesticides is recommended. Use cartridges with MSHA/NIOSH approval number TC-23C or canister with MSHA/NIOSH approval number TC-14G. Full facepiece replaces the need for chemical goggles.

Observe respirator use limitations specified by the manufacturers. Respiratory protection programs must comply with 29 CFR Part 1910.134.

For Application of Product Diluted in accordance with label instructions: Respirators are not required for applications of use - dilutions of this product.

Ventilation: No special precautions are recommended.

 

SECTION 9.  PHYSICAL AND CHEMICAL PROPERTIES

Appearance:            Light yellow liquid

Specific Gravity:     1.16 g/cm³(20 ^oC);

Odor:                         Odorless @ 23 degrees C

pH:                            4.0~7.5

NOTE: These physical data are typical values based on material tested but may vary from sample to sample.

Typical values should not be construed as a guaranteed analysis of any specific lot or as specifications for the product.

 

SECTION 10.  STABILITY AND REACTIVITY

Stability: Product is stable under normal conditions of storage and handling. Store in a cool, well-ventilated place away from foodstuffs, reducing agents and acids.

Materials To Avoid: Acids and bases.

Hazardous Decomposition Products: None

Hazardous Polymerization: Does Not Occur. This product can react with caustic (basic) materials to liberate heat. This is not a polymerization but rather a chemical neutralization in an acid base reaction.

 

SECTION 11.  TOXICOLOGICAL INFORMATION

Laboratory single exposure (acute) studies on this product indicate:

Eye Irritation rabbits:       Moderately irritating (including transient corneal opacity) to unrinsed eyes. Mildly irritating to rinsed eyes. Unrinsed eyes cleared by day 7 and rinsed eyes cleared by 72 hours.

Dermal LD50 rat:        Practically Non-toxic (>5000 mg/Kg)

Oral LD50 rat:             Practically Non-toxic (>5000 mg/kg)

Inhalation LC50 rat:    Slightly toxic (>2.05mg/L for 4 hrs.)

Skin Irritation rabbits: 4-hr exposure: Slightly irritating. Cleared in all animals within 72 hours.

ETHOXYLATED TALLOWAMINE:

The surfactant component of this herbicide is reported to cause irritation to the eyes and skin and may contribute to the irritation potential reported for this herbicide. Ingestion may produce gastrointestinal irritation, nausea, vomiting and diarrhea.

 

SECTION 12.  ECOLOGICAL INFORMATION

Ecological Information: This product has been shown to be slightly to moderately toxic in aquatic studies.

Rainbow Trout 96-hr LC50:            22 mg/L (static)

Rainbow Trout 96-hr LC50:            8.2 mg/L (dynamic)

Daphnia Magna 48-hr LC50:          37 mg/L (aeration)

Daphnia Magna 48-hr LC50:          24 mg/L (without aeration)

Bluegill Sunfish 96-hr LC50:          5.8 mg/L (dynamic)

Bluegill Sunfish 96-hr LC50:          14 mg/L (static)

Gammarus pseudolimnaeus 48-hr EC50:       42 mg/L

Fathead minnow 96-hr LC50:         9.4 mg/L

Channel Catfish 96-hr LC50:          16mg/L

Chinook Salmon 96-hr LC50:         20mg/L

Coho Salmon 96-hr LC50:              22 mg/L

Algae S. Capricornutum 72-hr EC50:           2.1 mg/L

This product has been shown to be practically non-toxic to avian species following subacute dietary exposure.

Bobwhite Quail 8-day LC50:          >6300 ppm

Mallard Duck 8-day LC50:             >6300 ppm

 

SECTION 13.  DISPOSAL CONSIDERATIONS

Disposal Considerations:      Do not contaminate water, foodstuffs, feed or seed by storage or disposal.

Waste Disposal Method:       Wastes resulting from the use of this product that cannot be used or chemically reprocessed should be disposed of in a landfill approved for pesticide disposal or in accordance with applicable Federal, state or local procedures. Emptied container retains vapor and product residue. Observe all label safeguards until container is destroyed.

Plastic Bottles and Non-Returnable Plastic Drums:    Do not reuse container. Triple rinse plastic container then puncture and dispose of in sanitary landfill, or by incineration, or, if allowed by state and local authorities, by burning. If burned, stay out of smoke.

Returnable/Refillable Containers:     After use, return the container to the point of purchase or designated locations. The container must only be refilled with this product. DO NOT REUSE THE CONTAINER FOR ANY OTHER PURPOSE. Prior to refilling, inspect thoroughly for damage such as cracks, punctures, abrasions and damaged or worn out threads on closure devices. Do not refill or transport damaged or leaking containers. Check for leaks after refilling and before transportation. If the container is not being refilled, return it to the point of purchase.

 

SECTION 14.  TRANSPORT INFORMATION

DOT Proper Shipping Name:                   Not Applicable.

DOT Hazard Class/I.D. No.:                     Not Applicable.

DOT Label:                                                Not Applicable.

SARA Title III: Immediate

Section 302: Not Applicable

Section 304: Not Applicable

Section 312: Not Applicable

Section 313: Not Applicable

 

SECTION 15.  REGULATORY INFORMATION

HMIS Rating:

              Health:         1

              Fire:             1

              Reactivity: 0

This product has been registered in China.

 

SECTION 16. OTHER INFORMATION

Disclaimer of Expressed and Implied Warranties:

The information contained herein is offered only as a guide to the handling of this specific material. No guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained here